2-(Adamantan-1-yl)-1,3-bis(4-methylphenyl)propan-2-ol
نویسندگان
چکیده
منابع مشابه
2-(Adamantan-1-yl)-1,3-bis(4-methylphenyl)propan-2-ol
The conformation of the title compound, C27H34O, is stabilized by a weak intra-molecular C-H⋯π inter-action. The dihedral angle between the benzene rings is 54.79 (4)°. The adamantane cage consists of three fused cyclo-hexane rings in classical chair conformations, with C-C-C angles in the range 107.75 (10)-111.35 (9)°. Although the mol-ecule contains a hy-droxy group as a conceivable hydrogen-...
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In the title compound, C(12)H(18)ClNO, which was synthesized as part of a study into potential anti-tuberculosis agents, the adamantine skeleton displays shorter than normal C-C bond lengths ranging between 1.5293 (18) and 1.5366 (15) Å. The structure also displays inter-molecular N-H⋯O hydrogen bonding, which forms an infinite chain in the a-axis direction.
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The title compound, C(16)H(24)O(3), has a cage-type mol-ecular structure and is of inter-est with respect to its photochemical properties. The structure displays non-classical inter-molecular C-H⋯O hydrogen bonding, which links the mol-ecules into a three-dimensional network.
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The five-membered ring in the the title mol-ecule, C(24)H(25)NO, fused with the phenyl-ene ring, is almost planar (r.m.s. deviation = 0.023 Å), with the methyl-ene C atom deviating most from this mean plane [0.031 (1) Å]. The tertiary N atom shows a flattened pyramidal configuration [Σ(angles at N) = 350.3 (6)°].
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In the title compound, C(23)H(25)NO, an intra-molecular O-H⋯N hydrogen bond defines the mol-ecular conformation; the naphthol mean plane and the benzene ring form a dihedral angle of 75.8 (2)°. The piperidine ring adopts a chair conformation. The crystal packing exhibits no short inter-molecular contacts.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812050647